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2-Methyl-5-phenylbenzoxazole

  • CAS No.: 61931-68-8
  • Purity: 99%
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High quality purity >99% 2-Methyl-5-phenylbenzoxazole 61931-68-8 for sale

  • Molecular Formula: C14H11 N O
  • Molecular Weight: 209.247
  • Appearance/Colour: Beige. 
  • Vapor Pressure: 9.16E-05mmHg at 25°C 
  • Melting Point: 58-59 ºC 
  • Refractive Index: 1.5780 (estimate) 
  • Boiling Point: 350ºCat 760 mmHg 
  • PKA: 1.49±0.10(Predicted) 
  • Flash Point: 144.7ºC 
  • PSA: 26.03000 
  • Density: 1.155 g/cm3 
  • LogP: 3.80320 

2-Methyl-5-phenylbenzoxazole(Cas 61931-68-8) Usage

InChI:InChI=1/C14H11NO/c1-10-15-13-9-12(7-8-14(13)16-10)11-5-3-2-4-6-11/h2-9H,1H3

61931-68-8 Relevant articles

COMPOUNDS HAVING PDE9A INHIBITORY ACTIVITY, AND PHARMACEUTICAL USES THEREOF

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Paragraph 0213, (2021/10/15)

The present invention provides a compoun...

Formal Carbene C-H Bond Insertion in the Cu(I)-Catalyzed Reaction of Bis(trimethylsilyl)diazomethane with Benzoxazoles and Oxazoles

Wang, Shuai,Xu, Shuai,Yang, Cheng,Sun, Hanli,Wang, Jianbo

supporting information, p. 1809 - 1812 (2019/03/28)

A Cu(I)-catalyzed cross-coupling reactio...

Inherent vs Apparent Chemoselectivity in the Kumada-Corriu Cross-Coupling Reaction

Hua, Xiye,Masson-Makdissi, Jeanne,Sullivan, Ryan J.,Newman, Stephen G.

supporting information, p. 5312 - 5315 (2016/11/02)

The Kumada-Corriu reaction is a powerful...

Regioselective syntheses of 2- and 4-formylpyrido[2,1-b]benzoxazoles

Li, Ke-Lai,Du, Zong-Bo,Guo, Can-Cheng,Chen, Qing-Yun

supporting information; experimental part, p. 3286 - 3292 (2009/09/08)

o-Acetaminophenols (2) reacted with Vils...

61931-68-8 Process route

5-bromo-2-methyl-1,3-benzoxazole
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5-bromo-2-methyl-1,3-benzoxazole

phenylboronic acid
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phenylboronic acid

2-methyl-5-phenylbenzo[d]oxazole
61931-68-8

2-methyl-5-phenylbenzo[d]oxazole

Conditions
Conditions Yield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium carbonate; In 1,4-dioxane; water; for 1h; Reflux;
96%
2-methyl-5-chlorobenzoxazole
19219-99-9

2-methyl-5-chlorobenzoxazole

triallyl(phenyl)silane
2633-57-0

triallyl(phenyl)silane

2-methyl-5-phenylbenzo[d]oxazole
61931-68-8

2-methyl-5-phenylbenzo[d]oxazole

Conditions
Conditions Yield
triallyl(phenyl)silane; With tetrabutyl ammonium fluoride; In tetrahydrofuran; water; at 20 ℃; for 1h;
2-methyl-5-chlorobenzoxazole; With XPhos; bis(η3-allyl-μ-chloropalladium(II)); In tetrahydrofuran; water; at 80 ℃; for 14h;
83%

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