.jpg)
Current location:Home > Organic Chemicals
High Quality Chinese Factory supply 101-64-4 VARIAMINE BLUE B BASE
- Molecular Formula: C13H14N2O
- Molecular Weight: 214.267
- Vapor Pressure: 3.01E-06mmHg at 25°C
- Melting Point: 101°C
- Refractive Index: 1.653
- Boiling Point: 210 °C / 4mmHg
- Flash Point: 188.9°C
- PSA： 47.28000
- Density: 1.178g/cm3
- LogP: 3.67520
VARIAMINE BLUE B BASE(Cas 101-64-4) Usage
|
General Description |
4-Amino-4'-methoxydiphenylamine is characterized by its structure, which includes a diphenylamine core with an amino group (-NH2) at the 4-position of one phenyl ring and a methoxy group (-OCH3) at the 4'-position of the other phenyl ring. It is commonly employed in the production of dyes, particularly in the synthesis of azo dyes, where its amino group can undergo diazo coupling reactions with other aromatic compounds to create a wide range of colorful dye molecules. Its role as a dye intermediate makes it important in the textile, ink, and pigment industries, contributing to the vibrant colors seen in various products. |
|
Purification Methods |
Crystallise the diamine from ligroin or *C6H6/pet ether (m 99-100o). The picrate has m 164o (from EtOH). [Beilstein 13 III 1161, 13 IV 1243.] |
InChI:InChI=1/C13H14N2O/c1-16-13-8-6-12(7-9-13)15-11-4-2-10(14)3-5-11/h2-9,15H,14H2,1H3
101-64-4 Relevant articles
-
Banthorpe,Cooper
, p. 605 (1968)
-
Efficient and Selective Oxidation of Aromatic Amines to Azoxy Derivatives over Aluminium and Gallium Oxide Catalysts with Nanorod Morphology
Singh, Bhawan,Mandelli, Dalmo,Pescarmona, Paolo P.
, p. 593 - 601 (2020)
Aluminium oxide and gallium oxide nanoro...
-
Hirashima,Manabe
, p. 259 (1975)
-
Discovery of a novel small-molecule inhibitor of Fam20C that induces apoptosis and inhibits migration in triple negative breast cancer
Chen, Lixia,Chen, Yanmei,Fu, Leilei,Liu, Bo,Liu, Yi,Sun, Dejuan,Wang, Leiming,Yuan, Zhaoxin,Zhang, Kai,Zhang, Lan,Zhao, Rongyan
, (2020/12/21)
The family with sequence similarity 20, ...
One-pot propagation of (Hetero)Arylamines: Modular synthesis of diverse Amino-di(hetero)arylamines
Liang, Xueting,Xu, Liang,Li, Cuihua,Jia, Xin,Wei, Yu
, p. 721 - 731 (2019/01/08)
Formal propagation of (hetero)arylamine ...
Design, synthesis and antitumor activity of novel cis-furoquinoline derivatives
Li, Jie,Pei, Shuchen,Zhu, Yingxi,Wu, Jianbo,Chen, Yin,Zhang, Weiyu,Wu, Yong
experimental part, p. 379 - 388 (2012/07/03)
A series of novel cis-furoquinoline deri...
101-64-4 Process route
-
-
104-94-9
4-methoxy-aniline
-
-
586-78-7
para-nitrophenyl bromide
-
-
101-64-4
Variamin Blau
| Conditions | Yield |
|---|---|
|
4-methoxy-aniline; para-nitrophenyl bromide;
With
tris-(dibenzylideneacetone)dipalladium(0); potassium carbonate; XPhos;
In
isopropyl alcohol;
at 110 ℃;
for 24h;
Inert atmosphere;
With
potassium tert-butylate; bis(pinacol)diborane;
In
isopropyl alcohol;
at 110 ℃;
for 4h;
chemoselective reaction;
Inert atmosphere;
|
66%
|
-
-
7696-66-4
4-methoxy-N-(4-nitrosophenyl)aniline
-
-
101-64-4
Variamin Blau
| Conditions | Yield |
|---|---|
|
With
titanium(III) chloride;
In
1,4-dioxane;
at 20 ℃;
for 4h;
|
85%
|
|
With
ammonium sulfide;
|
101-64-4 Upstream products
-
7696-66-4
4-methoxy-N-(4-nitrosophenyl)aniline
-
730-11-0
4-methoxy-N-(4-nitrophenyl)aniline
-
967-35-1
N-(4-methoxyphenyl)-2,4-dinitrobenzenamine
-
33836-66-7
5-amino-2-p -anisidino-benzenesulfonic acid
101-64-4 Downstream products
-
33840-14-1
[1,4]benzoquinone-imine-(4-methoxy-phenylimine)
-
101677-23-0
3-amino-2,4,6,8-tetrachloro-7-methoxy-phenothiazinylium; chloride
-
27163-30-0
4-Methoxy-4'-isothiocyano-diphenylamin
-
43096-14-6
N-{4-[4-(4-Methoxy-phenylamino)-phenylamino]-9,10-dioxo-9,10-dihydro-anthracen-1-yl}-benzamide
